Chemistry
Equilibria, acids and buffers
- 1.
Explain what is dynamic about equilibrium in a closed reversible reaction.
[3 marks] · no calculator - 2.
Distinguish a weak acid from a dilute acid, and explain whether dilution changes an acid's intrinsic strength at fixed temperature.
[3 marks] · no calculator - 3.
At equilibrium for H2 + I2 <=> 2HI, [H2] = 0.20, [I2] = 0.10 and [HI] = 0.40 mol dm^-3. Calculate Kc.
[3 marks] - 4.
Calculate the pH of 0.0200 mol dm^-3 HCl, assuming complete dissociation and negligible water contribution.
[3 marks] - 5.
A buffer contains HA and A^-. Explain separately how it resists added H+ and added OH-, and why a large addition can overwhelm it.
[4 marks] · no calculator - 6.
N2 + 3H2 <=> 2NH3 is exothermic. Evaluate increasing pressure and decreasing temperature to maximise industrial production, separating equilibrium yield from rate and operating cost.
[4 marks] · no calculator
Marking points are indicative, not an official mark scheme. Accept equivalent valid methods and supported interpretations that address the task; award each mark once without requiring the model wording.