Chemistry
Redox and electrochemistry
- 1.
For Mg -> Mg^2+ + 2e^-, identify oxidation or reduction and explain using electrons.
[3 marks] · no calculator - 2.
Explain the role of a salt bridge in a galvanic cell and why electrons do not travel through it.
[3 marks] · no calculator - 3.
Balance MnO4^- -> Mn^2+ as a reduction half-equation in acidic solution.
[3 marks] · no calculator - 4.
Standard reduction potentials are Cu^2+/Cu = +0.34 V and Zn^2+/Zn = -0.76 V. Calculate the standard cell potential and write the spontaneous overall reaction.
[3 marks] - 5.
A current of 1.93 A flows for 1000 s through Cu^2+ solution. Assuming 100% current efficiency, calculate deposited copper mass using F = 96500 C mol^-1 and M(Cu) = 63.5 g mol^-1.
[4 marks] - 6.
A positive standard cell potential predicts feasibility, but an iron object can corrode slowly in dry air. Explain why standard potential alone cannot predict its real corrosion rate.
[4 marks] · no calculator
Marking points are indicative, not an official mark scheme. Accept equivalent valid methods and supported interpretations that address the task; award each mark once without requiring the model wording.